Hexafluorosilicates of bis(carboxypyridinium) and bis(2-carboxyquinolinium)

Gelmboldt, V. O.; Koroeva, L. V.; Ganin, E. V.; Fonari, M. S.; Botoshansky, M. M.; Ennan, A. A.

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dc.contributor.author	Gelmboldt, V. O.	en
dc.contributor.author	Koroeva, L. V.	en
dc.contributor.author	Ganin, E. V.	en
dc.contributor.author	Fonari, M. S.	en
dc.contributor.author	Botoshansky, M. M.	en
dc.contributor.author	Ennan, A. A.	en
dc.date.accessioned	2021-09-29T09:52:41Z
dc.date.available	2021-09-29T09:52:41Z
dc.date.issued	2008
dc.identifier.citation	Hexafluorosilicates of bis(carboxypyridinium) and bis(2-carboxyquinolinium) / V. O. Gelmboldt, L. V. Koroeva, E. V. Ganin et al // Journal of Fluorine Chemistry. 2008. Vol 129, N 7. P. 632–636.	en
dc.identifier.uri	https://repo.odmu.edu.ua:443/xmlui/handle/123456789/10126
dc.description.abstract	The preparation and characterization of three isomeric carboxypyridinium and carboxyquinolinium hexafluorosilicate salts is described. The salts of the general formulas (LH)2[SiF6] (I–III, L = 2-carboxypyridine, 3-carboxypyridine, 4-carboxypyridine) and (LH)2[SiF6]2H2O (IV, L = 2-carboxyquinoline) were prepared from the protonation reaction of the corresponding pyridine carbonic acid by the fluorosilicic acid. The compounds were characterized by IR, mass-spectrometry, thermogravimetric analysis, solubility data, and in the case of III by X-ray crystallography. The relationship between the salts solubility and the H-bonding system was analysed.	en
dc.language.iso	en	en
dc.subject	Hexafluorosilicate	en
dc.subject	Heterocyclic amines	en
dc.subject	Solubility	en
dc.subject	Hydrogen bonding	en
dc.subject	Crystal structure	en
dc.title	Hexafluorosilicates of bis(carboxypyridinium) and bis(2-carboxyquinolinium)	en
dc.type	Article	en